奚桢浩
发布时间:2016-04-19   访问次数:24232   作者:



桢浩:

教授、博士生导师

联系方式:

地址:华东理工大学16517

座机:021-64253042    手机号:13564210998

Emailzhhxi@ecust.edu.cn

 

【个人简介】

2004.07  获华东理工大学化学工程与工艺专业学士学位;

2010.06  获华东理工大学化学工程专业博士学位;

2012.01-2013.02  美国威斯康辛大学麦迪逊分校访问学者;

2017.11-2017.12  法国国立应用科学院(INSA)访问学者。


【个人荣誉】

2016年第八届侯德榜化工科技青年奖

2018年中国石油和化学工业联合会青年科技突出贡献奖;

2019年第五届青年英才校长奖;

入选2016上海市青年科技启明星计划

入选2017年科技部中法杰出青年人才交流项目

入选2018上海市青年拔尖人才计划

入选2020年国家级青年人才


【社会兼职】

中国化工学会过程强化专业委员会第一届青年委员

上海市化学化工学会化学工程专业委员会委员

全国材料与器件科学家智库环境材料专家委员会委员


【研究方向】

围绕聚合物材料“高值化”、“高端化”、“工程化”开展应用基础研究:

1.复杂聚合反应行为辨识与链结构调控,实现聚合物高值化、柔性化

  • 定量描述聚合反应机理与动力学

  • 揭示高分子链结构演变规律与构效关系

  • 实现聚合过程精准建模与模拟,指导工程设计与优化运行

2.聚合反应过程流场调控与高效反应器

  • 研究非常规条件下的传递过程

  • 开发流场结构化高效酯化/聚合系列反应器

  • 创制流场结构化高效换热器、降膜脱挥器

3.高端聚合物创制与功能应用

  • 高性能共聚酯、共聚酰胺、弹性体、生物基聚合物可控制备

  • 高端液晶、聚酰亚胺等系列特种工程材料

  • 生物可降解组织工程支架材料

  • 功能聚合物基纳米材料

 

【承担项目】

5年主持十三五重点研发计划子课题、国家自然科学基金等国家项目5项,省部级项目5项,中国石化、烟台万华等企业重大产学研项目10多项:

  1. 国家重点研发计划子课题:聚酯/聚酰胺柔性聚合、纺丝全流程模拟优化(主持)

  2. 面上项目:桐油衍生物固化环氧大豆油过程的交联网络结构演变与固化行为研究(主持,)

  3. 面上项目:超临界发泡制备聚羟基乙酸及其共聚物三维支架过程的复杂相互作用及调控(主持)

  4. 中国石化十条龙攻关课题:千吨级 POE 中试关键技术研究及工艺包开发(主持)

  5. 中国石化十条龙攻关课题:千吨级高等规聚丁烯-1技术开发及工业示范(主持)

  6. 上海市人才计划项目(青年拔尖):高性能植物油基聚酯及其泡沫材料可控制备(主持)

  7. 上海市人才计划项目(青年科技启明星计划):微纳无机填料调控PET泡沫微观结构及性能的应用研究(主持)

  8. 中国石化:PAN原液脱挥及干喷湿纺全流程技术开发(主持)

  9. 中国石化:环己烷二甲酸二异壬酯模试研究及中试工艺包开发(主持)

  10. 中国石化:PA612中试研究及下游应用(主持)

  11. 中国石化:石油基/生物基生产聚碳酸酯中试工艺研究(主持)

  12. 中国石化:尼龙 MXD6 的合成工艺及应用研究(主持)

  13. 中国石化镇海炼化:高性能芳香族热致液晶聚酯制备技术研究(主持)

  14. 中国石化镇海炼化:聚丁烯-1变负荷过程换热/脱挥工艺装备研究(主持)

  15. 中石化上海石化研究院:长碳链尼龙1212聚合反应动力学研究(主持)

  16. 康泰斯(上海):台湾中石化 PCTG工艺包设计基础研究项目(主持)

  17. 万华化学:SAN聚合物溶液脱挥工艺研究与脱挥器设计(主持)

  18. 上海凯赛:戊二胺基聚酰胺/聚酯酰胺聚合过程开发(主持)

     

【主要成果】

1)参编专著:

  1. Qiuyu Tang, Yahua Chen, Huizhi Gao, Qian Li, Zhenhao Xi*, Ling Zhao, Chong Peng and Lanpeng Li. Chapter 8 in Soybean-Biomass, Yield  and  Productivity: Bio-Based  Epoxy  Resin  from  Epoxidized  Soybean  Oil, IntechOpen, Minobu Kasai, 2018.11, DOI: 10.5772/intechopen.81544.

  2. Ling Zhao, Tian Xia, Zhenhao Xi, Tao Liu. Chapter 3 in POLYMERIC FOAMS: Innovations in Processes, Technologies, and Products, CRC Press, Taylor & Francis Group, 2016.8 (著作)

    https://www.taylorfrancis.com/books/9781498738873.

2)近五年代表性论文:

  1. Tong Qin, Xun Pan, Zhenhao Xi*, Ling Zhao, Weikang Yuan. Macromolecular Chain Structure Regulation of AN-MA-IA Aqueous Copolymerization with a Water-Soluble Azo Initiator AIBA. Industrial & Engineering Chemistry Research.2021,60(23):8409-8419.

  2. Qiuyu Tang, Qian Li, Yunhan Luo, Xun Pan,Zhenhao Xi*, Ling Zhao. Development of an Innovative Biobased UV Coating Synthesized from Acrylated Epoxidized Soybean Oil and Poly(octamethylene maleate (anhydride) citrate).2021, doi/10.1021/acs.iecr.1c01258.

  3. Tong Qin, Zhenhao Xi*, Ling Zhao, Weikang Yuan. DFT Calculations on Initiation Kinetics of Water-Soluble Azo Initiators in Free-Radical Polymerization. Chinese Journal of Chemical Engineering, 2021.

  4. Jie Jiang, Qiuyu Tang, Xun Pan, Zhenhao Xi*, Ling Zhao, and Weikang Yuan. Structure and Morphology of Thermoplastic Polyamide Elastomer Based on Long-Chain Polyamide 1212 and Renewable Poly(trimethylene glycol). Industrial & Engineering Chemistry Research. 2020,59(39): 17502-17512.

  5. Chaobo Song, Jiapeng Zhang, Lian Cen, Zhenhao Xi*, Ling Zhao, Weikang Yuan. Modeling strategies for the degradation behavior of porous polyester materials based on their key structural features[J]. Industrial & Engineering Chemistry Research. 2020, 59(33):14806-14816.

  6. Chaobo Song, Yunhan Luo, Yankai Liu, Shuang Li, Zhenhao* Xi, Ling Zhao, Lian Cen, Eryi Lu, Fabrication of PCL Scaffolds by Supercritical CO2 Foaming Based on the Combined Effects of Rheological and Crystallization Properties, Polymers. 2020, 12(4):780.

  7. Jiapeng Zhang, Bowen Xie, Zhenhao Xi, Ling Zhao, Lian Cen, Ying Yan*. A comparable study of polyglycolic acid's degradation on macrophages' activation. Materials Science & Engineering. C- Materials for Biological Applications, 2020,109:110574.

  8. Jiapeng Zhang, Chaobo Song, Yuqing Han, Zhenhao Xi*, Ling Zhao, Lian Cen, Ying Yang. Regulation of inflammatory response to polyglycolic acid scaffolds through incorporation of sodium tripolyphosphate, European Polymer Journal. 2020,12: 109349.

  9. Shuang Li, Chaobo Song, Shengbing Yang, Weijun Yu, Weiqi Zhang, Guohua Zhang, Zhenhao Xi*, Eryi Lu*. Supercritical CO2 foamed composite scaffolds incorporating bioactive lipids promote vascularized bone regeneration via Hif-1α upregulation and enhanced type H vessel formation. Acta biomaterialia. 2019,94:253-267.

  10. Chaobo Song; Shuang Li; Jiapeng Zhang; Zhenhao Xi*, Eryi Lu*, Ling Zhao, Lian Cen. Controllable fabrication of porous PLGA/PCL bilayer membrane for GTR using supercritical carbon dioxide foaming, Applied Surface Science, 2019,472:82-92.

  11. Yujie Zhong, Jie Wang*, Zhenyu Yuan, Yu Wang, Zhenhao Xi*, Li Li, Zhiyong Liu, Xuhong Guo*. A Mussel-Inspired Carboxymethyl Cellulose Hydrogel with Enhanced Adhesiveness through Enzymatic Crosslinking. Colloids and Surfaces B: Biointerfaces. 2019,179:462-469.

  12. Zheng Xiangrui, Zhenhao Xi*, and Ling Zhao. Solvent strategy toward living cationic polymerization of trichloro (Nsilyl) phosphoranimine based on Density Functional Calculations and experimental verification. Chemical Engineering Journal. 2019, 377:1-9.

  13. Jie Tang, Bowen Xu, Zhenhao Xi*, Pan Xun, Zhao Ling. Controllable crystallization behavior of nylon-6/66 copolymers based on regulating sequence distribution[J]. Industrial & Engineering Chemistry Research, 2018, 57(44): 15008-15019.

  14. Zhang Jiapeng, Yang Shengbing, Yang Xi, Xi Zhenhao*, Zhao Ling, Cen Lian*, Lu Eryi, Yang Ying. Novel fabricating process for porous polyglycolic acid scaffolds by melt-foaming using supercritical carbon dioxide[J]. ACS Biomaterials Science & Engineering, 2018,4(2):694-706.

  15. Xi Zhenhao, Liu Tian, Si Wei, Bi Fengle, Xu Zhimei, Zhao Ling*. High-efficiency acetaldehyde removal during solid-state polycondensation of poly(ethylene terephthalate) assisted by supercritical carbon dioxide [J]. Chinese Journal of Chemical Engineering, 2018, 26(6): 1285-91.

  16. Qin Chunxi, Jie Tang, Xiaoyi Qiu, Zhenhao Xi*, and Ling Zhao. Improving particle flow in liquid-solid countercurrent extraction tower by insert structure optimization: A combined study on experiments and DEM simulations [J]. Powder Technology, 2018, 328:275-87.

  17. Bi Fenglei, Xiaoyi Qiu, Zhenhao Xi*, Ling Zhao, and Lianfang Feng. Decoupling Study of Melt Polycondensation of Polycarbonate: Experimental and Modeling of Reaction Kinetics and Mass Transfer in Thin Films Polycondensation Process [J]. Macromolecular Reaction Engineering, 2018, 12(3):1-9

  18. Yahua Chen, Zhenhao Xi*, Ling Zhao. Curing Kinetics of Bio‐based Epoxy Resin Based on Epoxidized Soybean Oil and Green Curing Agent[J]. AIChE Journal, 2017, 63(1): 147-153.

  19. Feng-Lei Bi, ZhenHao Xi*, and Ling Zhao. Reaction Mechanisms and Kinetics of the Melt Transesterification of Bisphenol-A and Diphenyl Carbonate, International Journal of Chemical Kinetics, 2018, 50: 188-203.

  20. Yahua Chen, Zhenhao Xi*, Ling Zhao. New bio-based polymeric thermosets synthesized by ring-opening polymerization of epoxidized soybean oil with a green curing agent[J]. European Polymer Journal, 2016, 84: 435-447.

  21. Zhenhao Xi, Jie Chen, Tao Liu, Ling Zhao*, Lih-Sheng Turng. Experiment and simulation of foaming injection molding of polypropylene/nano-calcium carbonate composites by supercritical carbon dioxide[J]. Chinese Journal of Chemical Engineering, 2016, 24(1):180-189.

     

3)代表性授权专利:

  1. 一种高压二氧化碳辅助的高效聚酯固相缩聚方法,ZL201410237802.4

  2. 一种链段结构均匀的高性能热致性液晶聚酯工业制备方法,ZL201410059629.3

  3. 塔式反应器及其连续生产聚酯多元醇的应用,ZL201210011282.6

  4. 连续生产聚酯多元醇的方法和装置,ZL201110364457.7

  5. 双釜串联工艺规模化制备热致性液晶聚合物的方法,ZL201410200044.9

  6. 绿色环氧树脂固化剂马来松香酸酐的一步法合成,ZL201610232189.6

  7. 一种高分子材料超临界流体微孔发泡三维成型装置及应用,ZL201510526955.5

  8. 一种具有微纳结构的组织工程支架材料及其制备方法,201810233788.9

  9. 一种高效脱挥塔内构件,ZL201820810179.0(实用新型) 

4)科技成果获奖:

  1. 2014年,上海市技术发明一等奖

  2. 2015年,第十七届中国专利优秀奖

  3. 2018年,中国石油和化学工业联合会科技进步一等奖

  4. 2019年,中国轻工业联合会科技进步二等奖

  5. 2019年,中国石油和化学工业联合会科技进步二等奖